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Napolean's armies invaded both Spain and Portugal.
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Padre Miguel Hidalgo took the first step toward in 1810. On September 16, 1810, he rang the bells of this village church so everyone can gather at the church in order for him to issue a call for a rebellion against the Spanish.
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Bolivar declares independence from Spain in 1811. Before he marched south into Bolivar had won Venezuela's independence in 1821.
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San Martin's Argentina had declared its independence. In 1817, San Martin led an army on a grueling march across the Andes to Chile.
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Several central american status declare their independence as well fro some crazy reason. Iturbide (who had declared himself emperor), refused to recognize the declarations of independence. He was finally over thrown in 1823.