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Archduke Francis Ferdinand of Austria-Hungary is assassinated by a Serbian nationalist before he became king. This event was the trigger of WWI.
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Because of the Archduke being assassinated, AH blames it on Serbia and declares war.
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Because of all of the alliances formed before WWI, Germany declares war on Russia.
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For the same reason Germany declared war on Russia, the ydeclare war on France.
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The United Kingdom declares war on Germay, as a reaction to Germany invading Belgium.
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AH declares war on Russia and Serbia declares war on Germany, another result of alliances and other triggers.
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America is announced to be neutral in the war by president Woodrow Wilson.
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The Battle of Tannenburg begins! This was fought between Russia and Germany in the first days of WWI.