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He was born on 4 of July in 1926 and he grew up in Barracas, Buenos Aires the city that he was born.His father was Alfredo Di Stéfano and her mother was Eulalia Laulhé Gilmont.His grandfather was the firts Di Stéfano in the family.
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The first game was with Rivaer Plate against Húracan. The follwing year was transerred at Húracan.
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On 1948 he participates with River Plate in South America Champions Cup, an official tournament Copa Libertadores predecessor, achieving the runner and scoring 4 goals in 6 games.
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His debut as Real Madrid took place on September 23, 1953 against Nancy Football Club of France in its presentation match that ended in defeat for 2-4 with the player scoring the last goal.
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With the arrival of Di Stefano, Real Madrid won eight of the next eleven league titles and one Copa del Generalissimo, Di Stéfano emerged as the top scorer in the league in five championships.
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Alfedro Di Stefano in 30 of January in1956 went to the selection of Spanish .He played his first game with the Spanish team playing the Dutch national team, match where Spain wins 5-1 with a hat-trick of Di Stéfano.
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Alfredo Di Stéfano on August 26, 1963, Di Stéfano was kidnapped in Caracas by the FALN (Armed Forces of National Liberation), a guerrilla group that operated in Venezuela during the sixties as the Madrid club disputed Small Club World Cup.
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3 of April in 1965 Alfredo Di Stéfano he played and retreating for Real Club Deportivo Spanish in Barcelona where he played two seasons was his last team as a player.Was honored by many teams but especially by the Real Madrid Football Club Celtic Football Club
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On 17 February 2008, received a tribute from representatives of world football for his career, which was delivered UEFA President Award from Michel Platini, the current president of UEFA. He was awarded the "Golden Guijuelo 2007" in Guijuelo, Salamanca.
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Video: His death On July 5, 2014 at 17:00, suffered a cardiac arrest during dinner celebrating his birthday. He rushed to the Hospital General Universitario Gregorio Marañón in Madrid died at 88 years of age.