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First to notice this layered structure composed of carbon atoms that are covalently to three other carbons. This forms a hexagonal shape that is a flat sheet
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Uses a technique called powder diffraction by seeing how x-rays reflected off the substance, they could estimate what it looked like on a molecular level
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He developed the idea of delocalized electrons in trying to understand the properties of graphite. He won the nobel prize for his work
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They showed a single layer of graphene for the first time. For decades scientists struggled to get a single layer of graphene for study. Most sections made were still 50-100 layers thick
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Used mechanical exfoliation (stripping off layers physically) but still nothing thinner than 50 layers
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Geim and Novoselov at the university of Manchester managed to get a single atom layer of graphene using the scotch tape technique. Used a piece of sellotape. They removed a single layer of graphene from a block of graphite. They then chemically dissolved the tape leaving only the graphene. They received the Nobel prize for their method.