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The Chinese who invented gunpowder (black powder) first used it in a weapon - gunpowder filled tubes aka rockets. Gunpowder is a flamible power, that explodes when lit.
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First recorded use of a firearm - shooter lit wicks by hand that ingnited gunpowder that was loaded into the gun barrel.
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The Fire Syphon was invented by Thracian Merchants. The Fire syphon was a large tube that launched Greek fire. Greek fire was well know for its devastating capability in naval battles. As it could burn on water.