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At this time they did not know anything about bookbinding, but the in the 400's the knew learned about the Papyrus Binding.
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Bookbinding was originated from the 1st century during the A.D's. The Romans of the time only created a simple book called codex by folding sheets of papyrus in half and sewing them through the fold. (Image: Lost Roman Codex hidden scrap part of the spine.)
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The Papyrus book was invented by the rorman time. THe used papyrus to make the books. They used the leaves for the paper and the string to tie them up together the ends of papyrus. This is the 4th century.
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This is the time were they invented an account binding for books. This took place in the 14th century.
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This is the Wooden Board book binding. This took place in the 16th century.
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This is the Vellum Binding. It took place in the 17th century.
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This is the Leather binding. It takes place in the 18th century.
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This is Paper case Binding. It, also, takes place in the 18th century.
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This is the in-boards cloth binding. It takes place in the 19th century.
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This is the cased cloth bindings. It takes place in the 19th century.
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This is the Contemporary Binding. It takes place in the late 19th century.
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Bookbinding these years are made complicated throughout special materials man made or can be made by using machines.