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Casteil saves Dean from Hell who is there suffering becuase he sold his soul to save his brother.
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Castiel chooses to disobey his orders because he no longer thinks that it is the right thing to do as the humans will die.
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Castiel dies holding off Raphael so that Dean can stop his brother Sam from breaking the last seal that prevents Lucifer from rising and bringing the apocalypse.
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Castiel gives up his angle status to save Sam and Dean whilst trying to stop Michael.
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Castiel dies to enable Sam enough time to regain control of his body and defeat Lucifer. He does this by sending Michael away temporarly using a holy fire. This action leads to his death when Lucifer kills him.
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Castiel went into Lucifers cage which was a difficault task in order to rescue Sam from eternal torture which he didn't deserve.
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Castiel stops Raphael who wants to raise Lucifer and Michael so they can have the battle that will bring the apocalypse that was God's plan.